The octahedron has 6 vertices, 12 edges and 8 faces, each of which is an equilateral triangle. The dual of an octahedron is a cube:
As dual polyhedra have the same symmetry groups, we have
        
Symm(Oct) = Symm(Cube) = S4.
Here we will just exhibit the three types of rotation axis for an
octahedron.